The Science of Campfires

This experiment comes from my neighbors at the Malibu Creek State Park campground. While taking my morning walk, I heard a lady bragging to her husband that she started the campfire with only one match. That made me think of the fellow that I watched the night before as he poured two bottles of charcoal lighter fluid onto a pile of wood and still failed to get the fire going. He would pour on the liquid and get a huge blaze, which quickly died. How could the heat of one match work better than a gallon of blazing lighter fluid?

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